Phenylenediamine-derived near infrared carbon dots: The kilogram-scale preparation, formation process, photoluminescence tuning mechanism and application as red phosphors

نویسندگان

چکیده

Kilogram-scale preparation of near infrared (NIR) carbon dots (C-dots) from o-phenylenediamine (o-PDA) with over 96% yield was reported in this study, and the estimated cost for each gram C-dots only $ 0.1. The formation process elucidated structural model also proposed which key intermediates were revealed. Excitingly, optical properties could be reversibly tuned via a facile protonation-deprotonation process. Upon protonation, fluorescence emission wavelength red shifted 47 nm, deprotonation enhance photoluminescence quantum by three times. These alterations attributed to stabilization excited electrons surface protons, diagrams showing electronic transition states according calculated band gaps. as prepared demonstrated themselves cheap readily available phosphors assembling LEDs.

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ژورنال

عنوان ژورنال: Carbon

سال: 2022

ISSN: ['0008-6223', '1873-3891']

DOI: https://doi.org/10.1016/j.carbon.2022.02.054